324620

Lithium bis(trimethylsilyl)amide

97%

Manufacturer: Sigma Aldrich

CAS Number: 4039-32-1

Synonym(S): Hexamethyldisilazane lithium salt

Select a Size

Pack Size SKU Availability Price
10 G 324620-10-G In Stock ₹ 8,952.28
50 G 324620-50-G In Stock ₹ 11,203.88
250 G 324620-250-G In Stock ₹ 37,173.05

324620 - 10 G

₹ 8,952.28

In Stock

Quantity

1

Base Price: ₹ 8,952.28

GST (18%): ₹ 1,611.41

Total Price: ₹ 10,563.69

Quality Level

200

Assay

97%

form

solid

density

0.860 g/mL at 25 °C (lit.)

SMILES string

[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

YNESATAKKCNGOF-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
225770
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 1,032.71 - ₹ 36,913.25
577928
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 4,459.90 - ₹ 21,065.45
766917
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 11,636.88 - ₹ 76,093.43
224367
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 4,459.90
577014
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 5,661.48
920398
Lithium bis(trimethylsilyl)amide
Sigma Aldrich ₹ 2,565.53 - ₹ 18,489.10

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Description

  • General description: Lithium bis(trimethylsilyl)amide is a non-nucleophilic strong Brønsted base, which is generally soluble in most of the nonpolar organic solvents. It is most commonly employed in organic reactions.[1][2]
  • Application: Base employed in generating enolates for the preparation of lactone precursors,[3] pyranones,[4] and cyclohexanes.[5]Used to catalyze the addition of phosphine P-H bonds to carbodiimides leading to phosphaguanidines.[6] Also used in a novel three-step synthesis of disubstituted 1,2,5-thiadiazoles.[7]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H228,H251,H314

Precautionary Statements

P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014

WGK

WGK 2

Flash Point(F)

62.6 °F

Flash Point(C)

17 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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0.860 g/mL at 25 °C (lit.)

SMILES string:
[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI:
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key:
YNESATAKKCNGOF-UHFFFAOYSA-N

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1S/C14H11F3N2O3/c1-7-10(14(15,16)17)3-2-4-11(7)19-12-9(13(21)22)5-8(20)6-18-12/h2-6,20H,1H3,(H,18,19)(H,21,22)

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JSXNJGKWSWRIGA-UHFFFAOYSA-N

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ICMWSAALRSINTC-UHFFFAOYSA-N

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CC(C)(C)CC(C)(C)c1ccc(O)cc1

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1S/C14H22O/c1-13(2,3)10-14(4,5)11-6-8-12(15)9-7-11/h6-9,15H,10H2,1-5H3

InChI key:
__