766917

Lithium bis(trimethylsilyl)amide solution

1.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 4039-32-1

Synonym(S): Hexamethyldisilazane lithium salt

Select a Size

Pack Size SKU Availability Price
100 ML 766917-100-ML In Stock ₹ 11,636.88
800 ML 766917-800-ML In Stock ₹ 76,093.43

766917 - 100 ML

₹ 11,636.88

In Stock

Quantity

1

Base Price: ₹ 11,636.88

GST (18%): ₹ 2,094.638

Total Price: ₹ 13,731.518

form

liquid

Quality Level

100

concentration

1.5 M in THF

density

0.893 g/mL at 25 °C

SMILES string

[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

YNESATAKKCNGOF-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
225770
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 1,032.71 - ₹ 36,913.25
324620
Lithium bis(trimethylsilyl)amide
Sigma Aldrich ₹ 8,952.28 - ₹ 37,173.05
577928
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 4,459.90 - ₹ 21,065.45
224367
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 4,459.90
577014
Lithium bis(trimethylsilyl)amide solution
Sigma Aldrich ₹ 5,661.48
920398
Lithium bis(trimethylsilyl)amide
Sigma Aldrich ₹ 2,565.53 - ₹ 18,489.10

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Description

  • General description: Lithium bis(trimethylsilyl)amide is commonly used in organic synthesis as a non-nucleophilic strong Bronsted base. It is soluble in most nonpolar solvents such as aromatic hydrocarbons, hexanes, and THF.
  • Application: Lithium bis(trimethylsilyl)amide can be used as a reagent:      In the deprotonation and nucleophilic difluoromethylation reactions.3-methoxy substituted dihydropyrrole derivatives by reacting with aldehydes and lithiated methoxyallene via in situ formations of N-trimethylsilylated imines.   In Darzens condensation and directed aldol condensation reactions.       To synthesize poly(N-octyl-p-benzamide)s by chain-growth polycondensation of 4-octylaminobenzoic acid methyl ester.

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H251,H314,H335,H336,H351

Precautionary Statements

P210 - P235 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 2

Flash Point(F)

31.3 °F

Flash Point(C)

-0.4 °C

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1.5 M in THF...


form:
liquid

Quality Level:
100

concentration:
1.5 M in THF

density:
0.893 g/mL at 25 °C

SMILES string:
[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI:
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key:
YNESATAKKCNGOF-UHFFFAOYSA-N

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1S/C7H8O2/c1-5-6(8)3-2-4-7(5)9/h2-4,8-9H,1H3

InChI key:
ZTMADXFOCUXMJE-UHFFFAOYSA-N

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OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI:
1S/C13HF25O2/c14-2(15,1(39)40)3(16,17)4(18,19)5(20,21)6(22,23)7(24,25)8(26,27)9(28,29)10(30,31)11(32,33)12(34,35)13(36,37)38/h(H,39,40)

InChI key:
LVDGGZAZAYHXEY-UHFFFAOYSA-N

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